Talk:MRD:bss15

HH System -'The 2nd derivative of the minima would be greater than 0 as the minima would be the lowest value on the 'valley' of a graph.' in all coordinates The TS would be a saddle point with a maximum in the reaction co ordinate.

MEPs start with zero momentum in each time step.

The main assumption of TS theory is that there is no re crossing of the TS. I think this is what you mean

HF System

How can it be observed experimently? You haven't answered this question.

'Set up 1 would require more energy than that of Set up 2.' What kind of energy this is very important. You havent shown a state with high vibrational energy here to try and prove Polyanis rules. Coming from the endothermic side