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Pentahelicene |
Pentahelicene |
Boraneamines tend to have close N−Hδ+···δ-H−B contacts as a result of the intermolecular interaction of the NH proton with the BH bond by a novel type of hydrogen bond (the dihydrogen bond). A CSD structural search provides characteristic metric data for the interaction: the H···H distance is in the range 1.7−2.2 Å, and the N−H···H group tends to be linear while B−H···H tends to be bent.<ref name="Blogs">None