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Tutorial: The Cope rearrangement

Optimising 1,5-hexadiene transition structures

1,5-hexadiene antiperiplanar conformer optimisation log file can be found here

1,5-hexadiene gauche conformer optimisation log file can be found here

1,5-hexadiene gauche3 conformer optimisation: lowest energy conformer log file can be found here

1,5-hexadiene antiperiplanar conformer re-optimisation log file can be found here

Frequency: here

Optimising the chair and boat transition structures

Optimisation of the allyl fragment log file can be seen here

Optimising the chair by calculating force constants log file can be seen here

Optimising the chair by the redundant coordinate editor log file can be seen here

Optimising the boat by QST2 log file can be seen here

Analysing the activation energies of the chair and boat transition structures log file can be seen:

Boat: here

Chair: here

Diels Alder Cycloaddition Exercise

Reacting ethane with cis-butadiene

Optimisation of cis-butadiene log file can be seen here

Transition state optimisation (Frozen) log file can be seen here

Transition state optimisation (Relaxed) log file can be seen here

IRC (100 steps) log file can be seen here

Reacting cyclohexa-1,3-diene with maleic anhydride

Optimisation of maleic anhydride log file can be seen here

Optimisation of cyclohexa-1,3-diene log file can be seen here

Optimisation of the exo transition state log file can be seen here

Exo transition state IRC log file can be seen here

Optimisation of the endo transition state log file can be seen here

Endo transition state IRC log file can be seen here