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Rep:Mod:Joh13 logfiles

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Log Files for Mod:Joh13


The Cope Rearrangement Tutorial

Optimising Reactants and Products

Optimising 1,5-Hexadiene Antiperiplanar Conformer

Anti1 optimisation: Media:ANTI1 CONFORMER JOH13.LOG

Optimising 1,5-Hexadiene Synperiplanar Conformer

Gauche6 optimisation: Media:GAUCHE6 CONFORMER JOH13.LOG

Optimising 1,5-Hexadiene Lowest Energy Conformer

Gauche3 optimisation: Media:GAUCHE3 CONFORMER JOH13.LOG

Optimising 1,5-Hexadiene Anti2 Conformer

Anti2 optimisation under Hartree Fock: Media:ANTI2 CONFORMER HF JOH13.LOG

Anti2 optimisation under DFT: Media:ANTI2 CONFORMER DFT JOH13.LOG

Frequency Analysis at 298.15 K

Anti2 frequency analysis: Media:ANTI2 CONFORMER FREQ JOH13.LOG

Optimising "Chair" and "Boat" Transition Structures

Optimised allyl fragment: Media:ALLYL FRAG JOH13.LOG

Chair Optimisation via Force Constant Calculation

Chair optimisation via force-constant method: Media:CHAIR FORCE CONSTANT OPT JOH13.LOG

Chair Optimisation via Freeze-Coordinate Method

Chair optimisation with frozen co-ordinates: Media:CHAIR CONFORMER FROZEN COORDS JOH13.LOG

Secondary optimisation with restrictions removed: Media:CHAIR CONFORMER FROZEN COORDS PT2 JOH13.LOG

Boat Optimisation via QST2 Method

Initial boat optimisation via QST2 method: Media:BOAT CONFORMER QST2 PT1 JOH13.LOG

Boat optimisation once reactant and product re-angled: Media:BOAT CONFORMER QST2 REANGLED JOH13.LOG

Boat Optimisation via QST3 Method

Boat optimisation via QST3 method: Media:BOAT CONFORMER QST3 JOH13.LOG

Intrinsic Reaction Coordinate of Transition Structures

IRC of chair structure obtained from the force-constant calculation: Media:CHAIR CONFORMER IRC JOH13.LOG

Activation Energies of Transition Structures

DFT 6-31G* of chair conformer: Media:CHAIR CONFORMER 631G JOH13.LOG

DFT 6-31G* of boat conformer: Media:BOAT CONFORMER 631G JOH13.LOG

DFT 6-31G* of anti 2 conformer: Media:ANTI2 CONFORMER DFT JOH13.LOG

Diels-Alder Cycloaddition Exercise

The Reaction of Cis Buta-1,3-diene with Ethene

Optimised cis buta-1,3-diene: File:BUTADIENE OPT JOH13.LOG

Optimised ethene: Media:ETHENE OPT JOH13.LOG

Optimisation of the Transition State

Optimised transition state with frozen co-ordinates: Media:DIELS ALDER FROZEN COORDS JOH13.LOG

Second optimisation without restraints: Media:DIELS ALDER TS JOH13.LOG

IRC calculation: Media:DIELS ALDER IRC JOH13.LOG

The Reaction of cyclohexa-1,3-diene with maleic anhydride

Cyclohexa-1,3-diene optimisation:Media:CYCLOHEXADIENE OPT JOH13.LOG

Maleic anhydride optimisation: File:MALEIC ANHYDRIDE OPT JOH13.LOG

Endo Transition state

Optimised structure with frozen co-ordinates: Media:ENDO FROZEN COORDS JOH13.LOG

Second optimisation without restraints: Media:ENDO OPT JOH13.LOG

IRC calculation: Media:ENDO IRC JOH13.LOG

Exo Transition state

Optimised structure with frozen co-ordinates: Media:EXO FROZEN JOH13.LOG

Second optimisation without restraints: Media:EXO OPT JOH13.LOG

IRC calculation: Media:EXO IRC JOH13.LOG