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Rep:Mod:CHEM1268251242251218001

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Data analysed for the optical rotation of (R)-2-phenyloxirane reported in literature

  • From the list below, only those values in chloroform were used for the literature average.

Summary

  • Average using all values as presented in literature = 8.978 deg.
  • Average found by converting all values to a negative sign = - 22.42 deg

Literature Data

Type Concentration Enantiomeric excess Length of Path Solvent Optical Rotatory Power Wavelength Temperature Location Reference
[alpha] 1.00 g/100ml chloroform -24 deg 589 nm 21 °C supporting information Bettigeri, Sampada V.; Forbes, David C.; Patrawala, Samit A.; Pischek, Susanna C.; Standen, Michael C.
Tetrahedron, 2009 , vol. 65, # 1 p. 70 - 76
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[alpha] 1 g/100ml 99 %ee 10 cm chloroform -19.5 deg 589 nm 20 °C Kroutil, Wolfgang; Schrittwieser, Joerg H.; Lavandera, Ivan; Mautner, Barbara; Seisser, Birgit; Lutje Spelberg, Jeffrey H.
Tetrahedron Asymmetry, 2009 , vol. 20, # 4 p. 483 - 488
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[alpha] 0.8 g/100ml 46 %ee benzene 21.5 deg 589 nm 22 °C Goswami, Amrit; Sarma, Kuladip; Goswami, Bhabesh C.
Tetrahedron Asymmetry, 2009 , vol. 20, # 11 p. 1295 - 1300
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[alpha] 33 deg 589 nm FERMENTA BIOTECH (UK) LIMITED
Patent: WO2007/135463 A1, 2007 ;
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[alpha] 0.652 g/100ml benzene 45.9 deg 589 nm 26 °C Fukuda, Tsutomu; Iwao, Masatomo; Kurosaki, Yuji
Tetrahedron, 2005 , vol. 61, # 13 p. 3289 - 3303
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[alpha] 1.01 g/100ml CHCl3 -23.7 deg 589 nm 31 °C Jacobsen, Eric N.; White, David E.
Tetrahedron Asymmetry, 2003 , vol. 14, # 22 p. 3633 - 3638
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[alpha] neat liquid 28.6 deg 589 nm 23 °C Brandes, Bridget D.; Furrow, Michael E.; Gould, Alexandra E.; Hansen, Karl B.; Jacobsen, Eric N.; Larrow, Jay F.; Schaus, Scott E.; Tokunaga, Makoto
Journal of the American Chemical Society, 2002 , vol. 124, # 7 p. 1307 - 1315
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[alpha] 0.8 g/100ml 10 cm CHCl3 -23 deg 589 nm 26 °C Capriati, Vito; Florio, Saverio; Luisi, Renzo; Salomone, Antonio
Organic Letters, 2002 , vol. 4, # 14 p. 2445 - 2448
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[alpha] 0.86 g/100ml benzene 10.7 deg 589 nm 25 °C Shi, Yian
Patent: US6348608 B1, 2002 ;
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[alpha] neat (no solvent) 33 deg 589 nm 18 °C Farmer, Peter B.; Matthews, Lee; Ellis, Martin K.; Cullis, Paul N.
Journal of Labelled Compounds and Radiopharmaceuticals, 1997 , vol. 39, # 6 p. 479 - 486
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[alpha] neat (no solvent) 34.3 deg 589 nm 20 °C McKinstry, Lydia; Myers, Andrew G.
Journal of Organic Chemistry, 1996 , vol. 61, # 7 p. 2428 - 2440
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[alpha] neat (no solvent) -24 deg 589 nm 20 °C Rieger, Bernhard; Jany, Gerhard
Chemische Berichte, 1994 , vol. 127, # 12 p. 2417 - 2420
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[alpha] 0.765 g/100ml benzene 42.7 deg 589 nm 23 °C Corey, E. J.; Helal, Christopher J.
Tetrahedron Letters, 1993 , vol. 34, # 33 p. 5227 - 5230
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[alpha] 2.47 g/100ml acetone 5.6 deg 589 nm 25 °C Pedragosa-Moreau, S.; Archelas, A.; Furstoss, R.
Journal of Organic Chemistry, 1993 , vol. 58, # 20 p. 5533 - 5536
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[alpha] 0.5 g/100ml CHCl3 -21.9 deg 589 nm 25 °C Hayashi, Masahiko; Miwata, Hiroshi; Oguni, Nobuki
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1991 , # 5 p. 1167 - 1171
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[alpha] 0.37 g/100ml diethyl ether -16.3 deg 589 nm 27 °C Ohta, Hiromichi; Matsumoto, Shinsuke; Sugai, Takeshi
Tetrahedron Letters, 1990 , vol. 31, # 20 p. 2895 - 2898
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[alpha] 3.09 g/100ml benzene 42.2 deg 589 nm 25 °C Imuta, Mitsuru; Kawai, Ken-ichi; Ziffer, Herman
Journal of Organic Chemistry, 1980 , vol. 45, # 16 p. 3352 - 3355
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[alpha] 16.5 deg 589 nm 25 °C Eliel; Delmonte
Journal of Organic Chemistry, 1956 , vol. 21, p. 596
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